Pyrolysis Learning

Pyrolysis


Workshop Plan
Pyrolysis Workshop

Tutor’s Booklet: Pyrolysis Workshop


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Workshop Presentation

Welcome Abroad

Welcome to the Pyrolysis Topic


Introductory Video

Discover insightful explanations and demonstrations in the following video.


Topic Orientation

Insightful Visuals

Informative Visuals of Pyrolysis Reaction.


Case Studies
1

Dow and Mura Technology’s Pyrolysis Plant in Bรถhlen, Germany

  • Dow and Mura Technology have partnered to build a pyrolysis plant in Bรถhlen, Germany.
  • The plant will convert mixed plastic waste into hydrocarbon liquids, which will be used by Dow to produce new plastics.
  • The facility will divert 120,000 metric tons of waste per year from incinerators and is expected to be the largest of its kind in Europe.
  • The partners plan to build additional facilities at Dow sites in Europe and the US, with a total capacity of 600,000 metric tons per year.
2

Nexus Circular’s Pyrolysis Process

  • Nexus Circular is a pyrolysis firm that focuses on dealing with heterogeneous inputs.
  • They aim to convert mixed plastic waste into uncontaminated feedstock for the production of new polymers.
  • The company emphasizes the challenge of dealing with the variability of feedstock and the need to select the appropriate temperature for breaking down different polymers.
3

Brightmark Energy Plant, Indiana

Brightmark Energy operates a pyrolysis plant that aims to recycle plastic waste into fuels such as diesel fuel, naphtha, and wax.


Software Application
Pyrolysis Kinetics Calculator

Step 1: Reaction Rate (k)


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The reaction rate constant (k) is a crucial parameter in pyrolysis kinetics. It depends on various factors, including temperature, feedstock composition, and the presence of a catalyst. Choose values that match your specific pyrolysis conditions.

Reaction Rate (k):

Step 2: Degree of Conversion (ฮฑ)


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The degree of conversion (ฮฑ) represents the fraction of reactant that has undergone pyrolysis. It depends on reaction time, temperature, feedstock composition, and the presence of a catalyst.

Degree of Conversion (ฮฑ):

Step 3: Reaction Orders (n and m)


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The reaction orders (n and m) determine how the reactants affect the reaction rate. Choose values for ‘n’ and ‘m’ that correspond to the reactant orders in your pyrolysis kinetics equation.

Reaction Orders (n and m):

Step 4: Calculate Output (dฮฑ/dt)


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Click the button to compute the output (dฮฑ/dt), the rate of weight loss at a given time, based on the parameters you’ve selected in the previous steps and the pyrolysis kinetics equation.

Output (dฮฑ/dt):

Flip The Cards
Scratch Card Quiz

Matching Words
Pyrolysis Energy Quiz

Match the terms with their definitions!

  • Terms
  • Biomass
  • Pyrolysis Process
  • Biochar
  • Syngas
  • Combustion
  • Gasification
  1.   is a thermal decomposition process that converts biomass into biochar, syngas, and other useful products.
  2.   is a solid, carbon-rich product of the pyrolysis process that can be used as a soil amendment or for other applications.
  3.   is a mixture of carbon monoxide, hydrogen, and other gases produced during the pyrolysis process, which can be used as a fuel.
  4.   refers to organic matter, such as plants or agricultural waste, that can be used as a feedstock for the pyrolysis process to produce energy.

Good Job !

There are still unanswered questions!


Smooth Quiz
Pyrolysis Quiz

Pyrolysis Quiz

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What is the process by which biomass is converted into energy?

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What is the primary material used in the production of biomass energy?


Entrepreneurial Spark
Pyrolysis Business App

Pyrolysis: Business Ideation



Seed Research Paper

Under Development, Stay Tuned!


Hands-On Kit

Experience hands-on learning with the educational practical kit.

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Formula Fundamentals

In the field of pyrolysis, several equations are used to describe the different aspects of the process. These equations help in understanding the kinetics, heat transfer, and mass transfer phenomena involved in pyrolysis. Here are some of the main equations used in the study of pyrolysis:

  1. Kinetic Equations:
    • Arrhenius equation: Describes the temperature dependence of the reaction rate in pyrolysis [1].
    • Reaction rate equations: Various reaction rate models, such as the first-order, nth-order, or parallel reactions, can be used to describe the conversion of biomass into different products during pyrolysis [1].
  2. Heat Transfer Equations:
    • Fourier's law of heat conduction: Describes the heat transfer through the solid biomass particles during pyrolysis [2].
    • Heat transfer coefficient equations: Empirical correlations or models are used to calculate the convective heat transfer coefficient between the solid particles and the surrounding gas [2].
  3. Mass Transfer Equations:
    • Fick's law of diffusion: Describes the mass transfer of volatile species from the solid biomass particles to the gas phase during pyrolysis [2].
    • Mass transfer coefficient equations: Empirical correlations or models are used to calculate the convective mass transfer coefficient between the solid particles and the surrounding gas [2].
  4. Energy Balance Equations:
    • Energy balance equation: Accounts for the energy transfer and conversion during pyrolysis, including the heat of reaction, sensible heat, and latent heat.
    • Conservation of energy equation: Balances the energy inputs and outputs in the pyrolysis system, including the heat supplied, heat losses, and heat absorbed by the products.

These equations, along with experimental data and other parameters, are used in mathematical models to simulate and predict the behavior of pyrolysis processes.


Learn more:

  1. 4.1 Biomass Pyrolysis | EGEE 439: Alternative Fuels from Biomass Sources
  2. ChemEngineering | Free Full-Text | Mathematical Modeling and Experiments on Pyrolysis of Walnut Shells Using a Fixed-Bed Reactor
  3. Mathematical Model of Pyrolysis of Biomass Particles - Tech Briefs

Supplementary Resources

Here are some credible references discussing the subject of Pyrolysis.

Reference TitleSource
"Pyrolysis" by the U.S. Department of Agriculture (USDA)USDA Research on Pyrolysis
"Pyrolysis of Biomass for Bioenergy" by the National Renewable Energy Laboratory (NREL)NREL Document on Pyrolysis
"Pyrolysis: An Overview" by the International Energy Agency (IEA)IEA Article on Pyrolysis
"Pyrolysis of Plastics" by ScienceDirectScienceDirect Article on Pyrolysis of Plastics
"Pyrolysis of Waste Tyres" by Bioresource TechnologyBioresource Technology on Tire Pyrolysis
"Pyrolysis of Biomass: A Review" by Renewable and Sustainable Energy ReviewsReview on Pyrolysis of Biomass
"Pyrolysis: A Sustainable Way to Manage Organic Waste" by the World Bioenergy AssociationWorld Bioenergy Association - Pyrolysis
"Pyrolysis: A Versatile Technology for Converting Biomass to Biofuels and Bioproducts" by the American Chemical SocietyACS Article on Pyrolysis
"Pyrolysis of Biomass to Biofuels: A Critical Review" by Energy & FuelsCritical Review on Pyrolysis of Biomass
"Pyrolysis of Waste: A Review" by Waste ManagementWaste Management - Pyrolysis Review

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